Basic characteristics and production status of Potassium bifluoride :
The Chinese name is potassium hydrogen fluoride or acid potassium fluoride, which is an inorganic compound with unique physical and chemical properties. This substance usually appears as colorless and transparent tetragonal crystals, which exist stably at room temperature, but are very "active" in nature. Most notably, its solubility – highly soluble in water and acidic in aqueous solutions, makes it an ideal acidic medium for many industrial processes.
In terms of production status, the main producers of Potassium bifluoride in the world are concentrated in industrially developed countries such as China, the United States, and Germany. According to the latest industry statistics, the global Potassium Bifluoride market size reached about $120 million in 2022 and is expected to grow to $180 million by 2028, with a compound annual growth rate of about 6.5%. This growth is primarily driven by expanding demand from industries such as the electronics industry, glass processing, and metal processing.
In terms of physical properties, Potassium bifluoride exhibits some notable behaviors. In dry air, it is able to remain stable and does not release hydrofluoric acid; However, in high-humidity environments, it quickly absorbs moisture and releases hydrofluoric acid gas. This feature poses both storage challenges and creates special industrial application value.
The following table summarizes the main physicochemical parameters of Potassium Bifluoride:
Property |
Value |
Remarks |
Molecular Weight |
78.11 g/mol |
- |
Melting Point |
~239°C |
Decomposes |
Density |
2.37 g/cm³ |
At 25°C |
Solubility |
39 g/100 mL water (20°C) |
Increases with temperature |
pH (1% aqueous solution) |
3-4 |
Weakly acidic |
From a safety perspective, Potassium Bifluoride is a corrosive substance that can cause severe burns when it comes into contact with the skin and eyes, and inhalation of its dust or gases can cause damage to the respiratory tract. Therefore, it is essential to wear appropriate protective gear when using it, including gas masks, chemical gloves, and goggles. The operating environment should be well ventilated to avoid long-term contact with metal, glass and other materials.
Multi-field core applications of Potassium Bifluoride
As a versatile chemical, Potassium Bifluoride plays an integral role in modern industry. Its wide range of applications and key role often exceed the imagination of ordinary people. From high-tech industries to traditional manufacturing, this compound exhibits unique value.
In the fluorine chemical industry, Potassium Bifluoride stands out in particular. It is an important electrolyte for the production of elemental fluorine, and this application stems from its unique electrochemical properties. During electrolysis, KHF₂ can effectively conduct current and participate in reactions, ultimately producing high-purity fluorine gas at the anode. As one of the most chemically reactive elements, fluorine gas plays an irreplaceable role in the preparation of fluorine-containing polymer materials (such as Teflon), fluorine-containing drugs and refrigerants.
The glass industry also uses Potassium Bifluoride in large quantities, mainly using its etching ability on glass. When it comes time to create graduated glass, art glass, or electronic display glass, KHF₂'s aqueous solution is able to react with silica to form soluble fluorosilicate, allowing for precise control of etch depth and pattern. Compared with traditional hydrofluoric acid etching, the use of Potassium Bifluoride is safer and more controllable, and the operating environment is more friendly.
In the world of metalworking, Potassium Bifluoride has shown multiple values. As a flux for welding and brazing, it effectively removes oxides from metal surfaces and promotes metallurgical bonding between metals. Especially in the welding of aluminum and stainless steel, KHF₂-based fluxes can significantly improve welding quality and efficiency. In addition, it is used for metal surface treatments, such as chemical polishing and stain removal of aluminum.
Wood preservative is a traditional but important application of Potassium bifluoride. As an effective preservative, it penetrates wood fibers, kills fungi and insects, and extends the life of wood. Compared with traditional arsenic-containing preservatives, KHF₂-treated wood is safer for the environment and human body, so it is increasingly preferred in the manufacture of children's play equipment and outdoor furniture.
Potassium Bifluoride also acts as a catalyst in organic synthetic chemistry. Especially in the alkylation reaction of benzene (such as the preparation of ethylbenzene and cumene), KHF₂ can significantly increase the reaction rate and selectivity, and reduce the formation of by-products. This application makes many petrochemical production processes more economical and environmentally friendly.
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